string.charCodeAt(index);

var str = new String("This is string"); 
console.log("str.charAt(0) is:" + str.charCodeAt(0)); 
console.log("str.charAt(1) is:" + str.charCodeAt(1)); 
console.log("str.charAt(2) is:" + str.charCodeAt(2)); 
console.log("str.charAt(3) is:" + str.charCodeAt(3)); 
console.log("str.charAt(4) is:" + str.charCodeAt(4)); 
console.log("str.charAt(5) is:" + str.charCodeAt(5));

str.charAt(0) is:84 
str.charAt(1) is:104 
str.charAt(2) is:105 
str.charAt(3) is:115 
str.charAt(4) is:32 
str.charAt(5) is:105